https://gw4869.com/index.php/a....pplying-the-threat-t
A 1,5-O → N carbamoyl move, an innovative new variation of this anionic Fries-type rearrangement, occurs when nitriles, imines, or alkylcarbodiimides are utilized. In these cases, the carbamoyl team plays a dual role as a directing team, building up a number of practical teams through the 1,5-O → N carbamoyl migration. Having said that, the usage of isthio)cyanates and arylcarbodiimides resulted in non-rearranged o-functionalized O-arylcarbamates. This reactivity was further computationally expl