https://ilreceptor-signal.com/....utilization-of-solut
This catalyst hydroborates alkynes with exceptional selectivities to the monoborylated anti-Markovnikov item (vinyl-boronate) when one equiv. of borane is employed. Very interestingly, aliphatic alkynes go through an additional hydroborylation process causing the corresponding 1,1- and 1,2-diboroylated species with great selectivities to the former.Herein two unprecedented octanuclear Co8 clusters are presented, [Cl@Co8 (TEOA)4(CH3CN)Cl3] (1) and [S@Co8(DEOA)6(NCS)2] (2) (H3TE
Like
Comment
Share
