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Our studies demonstrate how the interplay of changes in the reorganization energy and the damping factor of the molecular bridges, in addition to variation in the solvent polarity, affect the outcome of charge-transfer and the corresponding rate constants. The different regions of the Marcus parabola are highly relevant The charge-recombination of, for example, the adjacent C60•‒ ZnP•+ Fc charge-separated state is located in the inverted region, while that of the distant C60•‒ ZnP Fc•+ charge-separated state lies in the normal region. Here