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Both Eu(iii) complexes can detect citrate at extracellular concentrations up to 500 μM, even at millimolar concentrations of the other interfering species. In the case of the Eu(bisoQcd)OTf complex, an increase of 23% of the Eu(iii) luminescence intensity at 615 nm upon addition of 0.3 mM of citrate was recorded. This feature makes the latter complex a viable probe for luminescence analysis of citrate in a complex matrix.The discussion concerning cooperativity in supported single-atom (SA) catalysis is often limited to the metal-support in