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With a NiFe layered-double-hydroxide electrocatalyst, ZABs in line with the asymmetric cathode deliver a tiny charge/discharge voltage space (0.81 V at 5.0 mA cm-2 ), a top power thickness, and a well balanced cyclability (over 2000 rounds). This 3D reactive screen strategy provides a feasible method for boosting air cathode kinetics and additional enlightens electrode styles for energy products concerning multiphase electrochemical reactions. © 2020 WILEY-VCH Verlag Gm