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In today's research, Eu coordination and Eu(III)/Eu(II) electrochemical behavior as a function of liquid content in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][NTf 2 ]) had been investigated using UV-visible spectrophotometry, time-resolved laser fluorescence spectroscopy, electrochemistry, and X-ray consumption spectroscopy. In situ measurements were carried out in spectro-electrochemical cells. Under anhydrous conditions, Eu(III) and Eu(II) were complexed by NTf 2 , develo