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Valence tautomeric manganese(ii)-radical lamellar compounds [Mn2(NITIm)3]Xn with NITIm a nitronyl nitroxide radical and X = ClO4- (1) or BF4- (2) show a pressure-induced increase of their conversion temperature by approximately 40 K at a mild external pressure of 0.1 GPa, shifting the transition from near room temperature to hot temperature regions.Histone deacetylases play crucial roles in the regulation of chromatin structure and gene expression in the eukaryotic cell, and disruption of their activity causes a wide range of development

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