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The microstructures of wood samples were examined by the scanning electron microscopy, and the chemical functional groups were investigated by the Fourier transform infrared; both verified that the hydrophobic surface was successfully coated. The thermogravimetric examination revealed the improved thermal stability of the hydrophobic wood. The scratch test was used to measure the abrasion resistance of the nano and micron hollow mesoporous microsphere coatings on wood surface. It was suggested that the nano and micron hollow mesoporous mi