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Copyright © 2020 by S. Karger AG, Basel.Pneumopericardium is a relatively rare entity mostly described in the literature as a result of causes such as penetrating/blunt trauma and iatrogenic causes during cardiothoracic procedures. We are presenting a case of pneumopericardium as a complication of progressed gastroesophageal junction tumor along with a literature review of all cancer-related pneumopericardium cases reported in the last decade. We present the case of a 65-year-old male with a past medical history significant for locally a

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Probably the most favored [2 + 2] cycloreversions are the so-called regular Wittig-type reactions furnishing an alkene and a P═S-containing element. Significantly unfavored are responses relating to the P-S relationship cleavage and a C-to-P hydrogen shift in addition to a ring development to a 1,3,2-dithiaphospholane in case of high coordinate derivatives. Apart from a two-step P-to-S oxygen transfer in 1,2σ4λ5-thiaphosphetane P-oxide, a fascinating effect may be the P-S bond cleavage resulting in a thiab