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Modulating the local electronic state of metal compounds through interfacial interaction has become a key method for manufacturing high-performance hydrogen evolution reaction (HER) electrocatalysts. The electron-rich active sites can promote the adsorption of hydrogen, which accelerates the Volmer step and thereby enhances the electrocatalytic performance of HER. Here, we found that the strong interfacial interaction between TiO nanodots (TiO/Co-S) and Co-S nanosheets could advantageously improve the performance toward HER of electroca