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According to the computed D, the diffusivity of water tends to be larger when the (co)polymer is more hydrophobic and ΔG is more positive. D is actually seen to vary by orders of magnitude with the polymer structures, while the effect of the polymer species on the water permeation is stronger for ΔG than for D.We found emission intensity enhancement for fac-Ir(ppy)3 (ppy = 2-(2'-phenyl)pyridine) in aerated dimethyl sulfoxide (DMSO) during photoirradiation for the first time. This phenomenon was concluded to be responsible for the consum