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We will then discuss how the electrochemical performance of the electrodes/devices are affected by the various 3D-printing technologies and by manipulating the 3D-printed electrodes by post modification techniques. Finally, we will give our insights into the future perspectives of this exciting field based on our discussion through this Review.Structural, electrical, and thermal properties of CdSnAs2, with analyses from temperature-dependent transport properties over a large temperature range, are reported. Phase-pure microcrystalline p