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Our theoretical results offer a rational explanation for the air-stable and oxidation/moisture-resistant characteristics in moderately oxidized Sb2Se3 and may shed light on the surface oxidation-property relationship studies of other nonoxide semiconductor-sensitized devices.In this work, we reveal the dual roles of polymeric capping ligands in the hollowing of silica nanospheres during their surface-protected etching. We first show that polymeric capping ligands, if they have a stronger interaction with the surface Si-OH groups than water, can reduce the c