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Owing to its abundance, high theoretical capacity, and low electrode potential, zinc is one of the most important metallic anodes for primary and secondary batteries such as alkaline and zinc-air batteries. In the operation of zinc-based batteries, passivation of the anode surface plays an essential role because the electrode potential of zinc is slightly below that of the hydrogen evolution reaction. Therefore, it is important to scrutinize the nature of the passivation film to achieve anticorrosion inside batteries. Herein, the potential