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Passive daytime radiative cooling provides cooling without energy input. This method is eco-friendly, which is beneficial, considering the increasing problems of global warming and urban heat islands. A poly(vinylidene fluoride) (PVDF) and polyurethane acrylate (PUA) matte white coating was prepared via photo-initiated free-radical polymerization. The porous polymeric coating without a metal-reflective layer exhibited an average emissivity of 0.9333 in the atmospheric window and an average solar reflectance of 0.9336 in the direct AM1.5
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