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The main oxidizing hydroxyl radical (OH) and superoxide radicals (O2-) of the piezocatalytic reactions tend to be confirmed as well as the creation of piezocatalytic degradation procedure induced polarization electric charges. Furthermore, we investigate the relationship between morphology and piezoelectric prospective based on the finite element method for ZnO NPs and NRs, which further clarify the improved piezocatalytic activity and understanding of piezocatalytic device. This work