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Volcano analyses have been established as a standard tool in the field of electrocatalysis in order to assess the performance of electrodes in a class of materials. The apex of the volcano curve, where the most active electrocatalysts are situated, is commonly defined by a hypothetical ideal material that binds its reaction intermediates thermoneutral at zero overpotential, in correspondence to Sabatier's principle. However, recent studies in the literature reported a right shift of the apex in a volcano curve, in which the most active