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Herein, we report a technique for synthesizing colloidal crystals where the EEs are templated by little molecules, rather than NPs, and functionalized with a precise amount of DNA strands. When these molecularly precise EEs are put together with complementary NP-based PAEs, X-ray scattering and electron microscopy reveal the synthesis of three distinct "metallic" stages. Notably, we reveal that the thermal security of these crystals is based on the sheer number of gluey finishes per EE, while latti

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