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It can be seen that the accumulation of the 2,4-DNTs-3-SO3- is obviously larger than that of the 2,4-DNTs-5-SO3-, which may be related to the steric hindrance effect of sulfonic acid groups in the two isomers. Results showed DNTs distribution strongly linked to soil physicochemical properties and the migration of DNTs in soil exhibited obvious heterogeneity in time and space. The carcinogenic risks in surface soil (0-1.5 m) and lower soil (1.5-6.0 m, 6.0-8.0 m) are all higher than 1✕10-6; non-carcinogenic risk surface soil (0-1.5