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In this study, solvent exchange method was applied as a post-casting solvent treatment to tune the porosity and improve the performance of cellulose acetate/cellulose triacetate forward osmosis (CA/CTA FO) membrane. Ethanol and n-hexane were both used for this treatment as the first and second solvent, respectively. Pristine and treated CA/CTA FO membranes with different thicknesses were characterized using FESEM and adsorption/desorption analysis and also evaluated in terms of the intrinsic transport properties and structural parameter