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In decimolar aqueous solutions, zirconium oxychloride octahydrate forms several micrometer long and approximately 15 nm wide thin ribbons through the reaction with excess amounts of the sodium salt of 1-hydroxyethane-1,1-diphosphonic acid (HEDP, known as etidronic acid). Primarily deduced from SAXS, TEM, EXAFS and solid-state NMR analyses, a consistent structural model enables congruous explanations for the colloidal behaviour of the purified ribbons as well as of their reaction products with ammonia and amines, respectively. Properties
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