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The Principal Component Analysis showed that blueberry groups can be distinguished based on their phenolic compound profile.Large uptakes of nitrite have been proven to be detrimental to human health, therefore, the development of high-performance nitrite sensors is highly emergent. Herein, a carbon selenide nanofilms modified carbon fiber cloth (CSe2 NF/CC) electrode was obtained via in-situ synthesis to detect nitrite. The electrode integrates the collective merits of macroporous CC and pleated carbon selenide nanofilms, possessing a