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In PS We from T. elongatus, the excitation of long-wavelength chlorophyll (LWC) caused a pronounced electrochromic effect at 502 nm assigned towards the appearance of CT says of chlorophyll exciplexes. The synthesis of ion-radical set P700+A1- at 40 ps ended up being tied to energy transfer from LWC to the main donor P700 and associated with carotenoid bleach at 498 nm. In PS We from Synechocystis 6803, the excitation at 720 nm produced an immediate bidentate bleach at 690/7