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ures.In this paper, two phosphorescent Ir(III) complexes, Ir(ppy)2(Ln), were synthesized using 2-phenyl pyridine (ppy) as the first (major) ligand and two phosphorous compounds (L1 and L2) as the auxiliary ligand. Their single crystal structure and electronic structure were discussed. Ir(ppy)2(Ln) complexes were doped into a supporting matrix of bio-MOF-1 via cationic exchange to ensure their uniform distribution. Their successful doping was confirmed by SEM, fluorescence microscopy image, XRD, N2 adsorption/desorption and ICP measurement. Their photophysic