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Synchrotron-based X-ray absorption spectroscopy and scattering are known in situ probes of metal nanoparticles (NPs). A limited number of laboratory techniques allow post-synthesis diagnostics of the active metal surface area. This work demonstrates the high potential of infrared spectroscopy as an in situ laboratory probe for the growth of metal NPs on a substrate. We introduce a small fraction of CO molecules into the reaction mixture as a probe to monitor the reduction kinetics of the Pd2+ precursor on ceria in hydr

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0013) and 99% (p = 0.0002), respectively, compared to that in controls and abolished sorafenib-induced suppression of colony formation, possibly by modulating ERK and autophagy signals. Our findings demonstrate that sorafenib resistance mediated by FGL1 in HCC cells, suggesting FGL1 as a potential sorafenib-resistance biomarker and target for HCC therapy.Sexual health care for transgender people is often inadequate and not addressed. Targeted prevention approaches that respond to the specific needs of transgender individuals are essential