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Combining torrefaction with fast pyrolysis is an achievable route for producing long-chain ether precursors. The results of structural characterization for native and torrefied holocellulose indicated that with increasing torrefaction temperature, the crystallinity index (CrI) decreased slightly and then sharply increased; hydroxyls, O-acetyl branches, ether bond and β-1,4-glycosidic bond were eliminated but carbonyls increased. Maximum mass loss rate and apparent activation energy increased after torrefaction. With an increase in torre
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