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The feasibility of removal of chemical oxygen demand (COD) and ammonia nitrogen (NH4+-N) from landfill leachate by an electrochemical assisted HClO/Fe2+ process is demonstrated for the first time. The performance of active chlorine generation at the anode was evaluated in Na2SO4/NaCl media, and a higher amount of active chlorine was produced at greater chloride concentration and higher current density. The probe experiments confirmed the coexistence of hydroxyl radical (•OH) and Fe(IV)-oxo complex (FeIVO2+) in the HClO/Fe2+ system. The