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© 2020 Wiley Periodicals, Inc.This article discloses a new horizon for the application of peroxides in medical chemistry. Stable cyclic peroxides demonstrated cytotoxic activity against cancer cells, besides a mechanism of cytotoxic action was proposed. Synthetic bridged 1,2,4,5-tetraoxanes and ozonides were effective against HepG2 cancer cells and some ozonides selectively targeted on liver cancer cells (SI for compounds 11b and 12a is 8 and 5 respectively). Tetraoxanes and ozonides in some cases were more specific than that of paclita
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