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Furthermore, Ni-COF is stable for over 65 h during electrochemical testing. This work provides an accelerating strategy for the design of new porous crystalline-material-based electrocatalysts.Solid-state batteries have significant advantages over conventional liquid batteries, providing improved safety, design freedom, and potentially reaching higher power and energy densities. The major obstacle in the commercial realization of solid-state batteries is the high resistance at the interfaces. To overcome this bottleneck, it is essential