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Transcending phenomenon, self-assembly of synthetic molecules is now becoming an essential tool to design supramolecular materials not only in the thermodynamically stable state but also in kinetically trapped states. However, an approach to design complex self-assembly comprising different types of self-assembled states remains elusive. Herein we demonstrate an example of such systems based on our unique supramolecular polymer mediated by supermacrocyclization of hydrogen-bonding π-conjugated molecule. By adding an aromatic solvent in