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A number of advanced spectroscopic analyses disclosed that the photocatalytic oxic pre-treatment led to breakdown of chemically inert, electron mediating and chromophoric aromatic macrostructure of HA to make smaller sized oxygenated organic intermediates. These intermediates had been more nucleophilic than the pristine HA and acted as sacrificial reagent within the subsequent anoxic procedure to enhance H2 production. This study showcases an electricity recuperating liquid remediation