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The transformation from the traditional potentiometric response of an ion-selective electrode (ISE) to other signal readout is promising to realize the potential signal amplification. In this work, the redox probes, including ferrocyanide/ferricyanide (Fe(CN)63-/4-), hexaammineruthenium (Ru(NH3)63+) and ferrocene derivatives, were introduced to read out the potentiometric response for the solid-contact Ca2+-ISE. The mechanism is that the oxidation current of the redox probe on a glassy carbon electrode is modulated by the potential of t
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