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https://www.selleckchem.com/pr....oducts/proxalutamide
Quantitative analysis of the kinetic data demonstrated that Red/e - react ~5 times faster than Blue/e - with the nitroxyl radical oxidant, 4-MeO-TEMPO. Similar reactivity patterns were also observed in oxidations of TiO2/e - by O2, which like 4-MeO-TEMPO is a proton-coupled electron transfer (PCET) oxidant, and by the pure electron transfer (ET) oxidant KI3. This suggests that the faster intrinsic reactivity of one trap state over another on the seconds-minutes timescale is likely a general feature of reduced TiO2 reactivit