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Furthermore, there is no change in the extent of conformational chirality between the NTB and N phases. Using single-molecule stochastic dynamics simulations in the gas phase, we study the dimer series CBnCB (where n = 6, 7, 8 or 9) and CBCH2)5YCB (where X/Y = CH2, O or S) in terms of the bend angle and conformational chirality. We confirm that the bent molecular shape determines the ability of a dimer to exhibit the NTB phase rather than its potential to assume chiral conformers; as |χ|max increases with the spacer length, but the ev
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