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X-ray crystal structures of 1b and 2b are provided. Interestingly, complex 1b is polymeric n into the solid state, as a result of inter-molecular Hg-O connections, and functions rare three coordinate mercury websites with a T-shaped arrangement, whereas the (t-Bu-maloNHCDipp)HgCl (2b) is monomeric and it has a linear, two-coordinate mercury center. The forming of T-shaped structure while the aggregation of complex 1b is attributable to the paid down steric need of the N-heterocyclic carben
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