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To further reduce the uncertainty of isotope-based source apportionment results, more laboratory and field studies are necessary to refine the δ15N(NH3) source profile of NH3 using validated collection technique as overlapping exist between δ15N(NH3) values in agricultural sources such as livestock breeding waste (-42.5‰ to -29.1‰) and fertilizer application (-51.5‰ to -35.0‰).Smoking cigarettes and drinking coffee are common habits in today's society. However, it is not easy to get up-to-date information on smoking prevalence and caffe