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The reaction of propargylic amines and CO 2 can efficiently reduce the release to carbon dioxide and provide many high value-added chemical products. Nevertheless most of catalysts in such reaction were associated with noble-metal to obtain high yield, and it is necessary and important to seek eco-friendly noble-metal-free MOFs catalysts, but have not been reported so far. Here a giant and lantern-like [Zn 116 ] nanocage in zinc-tetrazole 3D framework [Zn 22 (Trz) 8 (OH) 12 (H 2 O) 9 ·8H 2 O] n Trz = (C 4 N 12 O) 4- ( 1 ) was obtained