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https://www.selleckchem.com/pr....oducts/cobimetinib-g
The syntheses of [RuVI(Por)(NAd)(O)] and [RuVI(2,6-F2-TPP)(NAd)2] have been described. [RuVI(2,6-F2-TPP)(NAd)(O)] capable of catalysing aerobic epoxidation of alkenes has been characterised by X-ray crystallography with Ru[double bond, length as m-dash]NAd and Ru[double bond, length as m-dash]O bond distances being 1.778(5) Å and 1.760(4) Å (∠O-Ru-NAd 174.37(19)°), respectively. Its first reduction potential is 740 mV cathodically shifted from that of [RuVI(2,6-F2-TPP)(O)2].It has been challenging to detect small ana