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Application of 20% finer BC particles is the optimal for stormwater retention in all BC addition substrates. Moreover, it could reduce the roof upper surface temperature by 3-5 °C and reduced the daily heat gain of the green roof by at least 0.06 MJ/m2 compared with BC-free ones. Overall, adding BC into the substrates of green roofs can achieve better hydrothermal properties, which is beneficial to the design optimization of green roofs.Fe/S-bearing erdite flocculant has been proven to be effective in the precipitation of heavy metals f