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This work demonstrates a facile strategy for constructing scaffolded catalytic nanomachineries to biosynthesize valuable metabolites in bacterial cells, and a unique assembly induced the switch-on mechanism in biosynthesis for the first time.The brightness of organic fluorescence materials determines their resolution and sensitivity in fluorescence display and detection. However, strategies to effectively enhance the brightness are still scarce. Conventional planar π-conjugated molecules display excellent photophysical properties as isol
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