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This work aims to prepare the silicon nanoparticles with the nanocrystal-embedded amorphous structure through spark erosion followed by bead milling. Spark erosion breaks up monocrystal silicon ingots into micro/nanoparticles, refines the crystal grains, makes the crystals randomly disordered, and increases isotropic character. Bead milling further refines the crystal grains to a few nanometers and increases the amorphous portion in the structure, eventually forming an amorphous structure with the nanocrystals embedded. Spark erosion sav