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The spheres were synthesized utilizing quite a lot of dangerous and toxic waste, red mud (50 wt% of solid elements), whoever recycling is challenging. The inorganic polymeric spheres, compared to virgin alkaline raw materials, enhanced organic matter reduction by 44%, prevented VFA accumulation (acidification degree less than 20%), maintained pH values in a variety (6.5-7.2) assuring maximum methanogenic activity by archaea microorganisms, and boosted the