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The transformation of halogenated organics in advanced oxidation processes (AOPs) has been extensively investigated. However, we currently know little about the fate of halogenated pollutants in the presence of exogenic halides (Cl- or Br-). Herein, the degradability, mineralization rate, and accumulation capacity of adsorbable organic halogen (AOX) for chlorophenols (2-chlorophenol (2-CP), 3-chlorophenol (3-CP), 4-chlorophenol (4-CP), and 2,4,6-trichlorophenol (TCP)) were compared in the Fe2+/persulfate (PS) process with the addition o