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Revealing the intrinsic origin is critical for developing performance-enhancing V2O5 battery-type electrode materials. In this work, ultralong single-crystal V2O5 wires (W-V2O5) and V2O5 plate particles (P-V2O5) with similar physicochemical properties were compared to investigate the possible stimulative factors for pseudocapacitive enhancement. Our results indicate that besides the most-discussed specific surface area (or nanostructure), the enhanced electronic conductivity, the controllable interlamellar spacing distance, and the ion-