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One important principle is that solutions for water challenges should not introduce new environmental and social problems. This Review aims to highlight the role of 2D photothermal nanomaterials in solving water challenges and provides a viable scheme toward the practical use in photothermal materials selection, design, and evaporation systems building. © 2020 The Authors. Published by WILEY‐VCH Verlag GmbH Co. KGaA, Weinheim.Although carbon itself acts as a catalyst in various reactions, the classical carbon materials (e.g., activ