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Nano-XANES ended up being made use of to review the trace additional stages in lithium metal phosphate (LFP) particles. We observed specific Fe-phosphide nanoparticles in pristine LFP, whereas partly (de)lithiated particles showed Fe-phosphide nanonetworks. These conclusions shed light from the contradictory reports on Fe-phosphide morphology within the literary works. Nano-XANES bridges the capability space of spectromicroscopy methods and offers interesting research possibilities across multiple dis