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On the basis of the experimental results, the mechanism of this installation framework variation of CTAB at first glance of negatively charged AuNPs had been proposed. For a given level of AuNPs, the installation framework of CTAB on the surface of AuNPs undergoes the change from a monolayer to a bilayer with all the increase of CTAB. In the case of the focus of CTAB far beyond its critical micelle concentration (CMC) additionally the greater ratio of CTAB and AuNPs, there is certainly