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Weak Van der Waals' interactions between interlayers of two-dimensional layered materials have rendered intrinsic problems of disabled across-interlayer electron transfer and poor layered structural stability, seriously deteriorating their performance in energy applications. Herein, we propose a novel covalent assembly strategy for MoS 2 nanosheets to realize unique MoS 2 /SnS hollow superassemblies (HSs) by using SnS nanodots as covalent linkages. The covalent assembly based on all-inorganic and carbon-free concept enables effective ac