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The efficiency of Ni0.8Fe0.2(OH)2 electrocatalyst is reflected in its low Tafel slope (43 mV dec-1) and high OER faradaic efficiency (93%). The enhanced activity is attributed to the increase in the interlayer spacing due to the intercalation of EG into the material, which facilitates the transport of ions during the OER process. The overall improved catalytic property is due to the enhanced ionic mobility, controllable textural property, higher per-site activity and increased conductivity for the Ni0.8Fe0.2(OH)2 catalytic network.The si