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26 eV, while the corresponding electronic bandgap of VO2( based on the HSE functional possesses a larger band gap of 0.67 eV. The prediction of optical characteristics of VO2( indicated that the optical conductivity of VO2( lies in the infrared region of light. This work strongly suggests the combination of GGA/PBEsol with HSE hybrid functionals to carefully describe the physical properties of smart materials exploitable in electronics and optoelectronics applications. The nanostructure of VO2( looks promising for IR photodetect